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The Temperature Dependence of Homogeneous Nucleation Rates by the Gradient Theory
Hrubý, Jan
We demonstrate that the incorrect temperature dependence of the nucleation rates as predicted by the classical nucleation theory is likely a consequence of the ignored dependence of the surface tension on the radius of the droplet parameterized here as a quadratic function of the pressure difference between the gas and liquid phases of the critical cluster. The size-dependent surface tension is obtained using a simplified gradient theory.

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